Tunable coordination of a tropos phosphite for fine-tuning of the Rh catalyzed asymmetric addition of phenylboronic acid to cyclohexenone.
نویسندگان
چکیده
Using the deoxycholic acid derived tropos biphenylphosphite as a Rh(i) chiral ligand different complexes are obtained, depending on the Rh : L molar ratio, that give rise to the formation of different chiral products in the asymmetric addition of phenylboronic acid to cyclohexenone.
منابع مشابه
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ورودعنوان ژورنال:
- Chemical communications
دوره 4 شماره
صفحات -
تاریخ انتشار 2009